IMPLEMENTACIÓN DE UNA METODOLOGÍA ELECTROQUÍMICA DE BAJO COSTO PARA EL ANÁLISIS DE DIAZINON EN SUELO

Irene Castillero Rosales; Denis Vega Montenegro

Submitted July 20, 2022

Published 2022-07-20

Artículos

Vol. 24 No. 2 (2022): Tecnociencia

IMPLEMENTATION OF A LOW-COST ELECTROCHEMICAL METHODOLOGY FOR THE ANALYSIS OF DIAZINON IN SOIL

Irene Castillero Rosales⁺⁻
Denis Vega Montenegro⁺⁻

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DOI: ND

Published: 2022-07-20

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Castillero Rosales, I. and Vega Montenegro, D. (2022) “IMPLEMENTATION OF A LOW-COST ELECTROCHEMICAL METHODOLOGY FOR THE ANALYSIS OF DIAZINON IN SOIL”, Tecnociencia, 24(2), pp. 118–139. Available at: https://revistas.up.ac.pa/index.php/tecnociencia/article/view/3077 (Accessed: 24 November 2024).

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Abstract

For the first time at the University of Panama, a methodology was implemented for the extraction of pesticide residues in soils through extraction assisted by sonication in small columns (SAESC), a novel, fast and green methodology, since in its application Analysis time is reduced compared to classical techniques by up to 92% and solvent consumption by 98%. The multi-residue extraction technique was evaluated with the classical gas chromatography technique to confirm the extraction efficiency. It is shown that the technique is capable of quantitatively extracting analytes in the multiresidue mode.

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References

Arienzo, M., Sánchez-Camazano, M., Sánchez-Martín, M., y Crisanto, T. (1994). Influence of exogenous organic matter in the mobility of diazinon in soils. Chemosphere, 29(6), 1245–1252. https://doi.org/10.1016/0045-6535(94)90255-0

Badii, M. H., y Varela, S. (2015). Insecticidas Organofosforados: Efectos sobre la Salud y el Ambiente. Cultura Científica Y Tecnológica, (28). Recuperado a partir de https://erevistas.uacj.mx/ojs/index.php/culcyt/article/view/375

Castro, J., Sánchez-Brunete, C., y Tadeo, J. (2001). Multiresidue analysis of insecticides in soil by gas chromatography with electron–capture detection and confirmation by gas chromatography–mass spectrometry. Journal of Chromatography A, 918(2), 371–380. https://doi.org/10.1016/s0021-9673(01)00751-8

Colborn, T., Dumanoski, D., y Myers, J. P. (1997). Our Stolen Future: Are We Threatening Our Fertility, Intelligence, and Survival?--A
Scientific Detective Story (First Printing ed.). Plume.

?Olovi?, M., Krsti?, D., Petrovi?, S., Leskovac, A., Joksi?, G., Savi?, J., Franko, M., Trebše, P., y Vasi?, V. (2010). Toxic effects of diazinon and its photodegradation products. Toxicology Letters, 193(1), 9–18. https://doi.org/10.1016/j.toxlet.2009.11.022

Edwards, G. A., Bergren, A. J., y Porter, M. D. (2007). Chemically Modified Electrodes. Handbook of Electrochemistry, 295–327. https://doi.org/10.1016/b978-044451958-0.50021-5

Eisler, R. (2000). Handbook of Chemical Risk Assessment: Health Hazards to Humans, Plants, and Animals, Three Volume Set (1st ed.). CRC Press.

El-Gendy, K., Mosallam, E., Ahmed, N., y Aly, N. (2018). Determination of glyphosate residues in Egyptian soil samples. Analytical Biochemistry, 557, 1–6. https://doi.org/10.1016/j.ab.2018.07.004

Erdo?du, G. (2003). A sensitive voltametric method for the determination of Diazinon Insecticide. Journal of Analytical Chemistry, 58(6), 569–572. https://doi.org/10.1023/a:1024120320359

Espinosa J. (1984). Plaguicidas. Revista Miscelánea, 3, 10-20.

Gamez, M. J. (2022, May 24). Objetivos y metas de desarrollo sostenible. Desarrollo Sostenible. https://www.un.org/sustainabledevelopment/es/objetivos-de-desarrollo-sostenible/

Garcia J. (1999). Análisis preliminar del uso de plaguicidas en la Cuenca del Río Tempisque. Revista Acta Académica, Universidad Autónoma de Centro América, 25, 51-62.

Glavan, G., Kos, M., Boži?, J., Drobne, D., Saboti?, J., y Kokalj, A. J. (2018). Different response of acetylcholinesterases in salt- and detergent-soluble fractions of honeybee haemolymph, head and thorax after exposure to diazinon. Comparative Biochemistry and Physiology Part C: Toxicology & Pharmacology, 205, 8–14. https://doi.org/10.1016/j.cbpc.2017.12.004

Gulaboski, R., Ferreira, E. S., Pereira, C. M., Cordeiro, M. N. D. S., Garau, A., Lippolis, V., y Silva, A. F. (2007). Coupling of Cyclic Voltammetry and Electrochemical Impedance Spectroscopy for Probing the Thermodynamics of Facilitated Ion Transfer Reactions Exhibiting Chemical Kinetic Hindrances. The Journal of Physical Chemistry C, 112(1), 153–161. https://doi.org/10.1021/jp076203s

Guziejewski, D., Skrzypek, S., y Ciesielski, W. (2011). Square wave adsorptive stripping voltammetric determination of diazinon in its insecticidal formulations. Environmental Monitoring and Assessment, 184(11), 6575–6582. https://doi.org/10.1007/s10661-011-2442-7

Koryta, J., Dvorak, J., y Kavan, L. (1993). Principles of Electrochemistry (2nd ed.). Wiley.

Lazarevi?-Pašti, T. D., Bondži?, A. M., Pašti, I. A., Mentus, S. V., & Vasi?, V. M. (2013). Electrochemical oxidation of diazinon in aqueous solutions via electrogenerated halogens – Diazinon fate and implications for its detection. Journal of Electroanalytical Chemistry, 692, 40–45. https://doi.org/10.1016/j.jelechem.2013.01.005
Li, M., Li, Y. T., Li, D. W., y Long, Y. T. (2012). Recent developments and applications of screen-printed electrodes in environmental assays—A review. Analytica Chimica Acta, 734, 31–44. https://doi.org/10.1016/j.aca.2012.05.018

Liu, Y., Song, C., Li, Y., Liu, Y., y Song, J. (2011). The distribution of organochlorine pesticides (OCPs) in surface sediments of Bohai Sea Bay, China. Environmental Monitoring and Assessment, 184(4), 1921–1927. https://doi.org/10.1007/s10661-011-2089-4

Lourenço AS, Sanches FA, Magalhães RR, Costa DJ, Ribeiro WF, Bichinho KM, Salazar-Banda GR, y Araújo MC. 2014. Electrochemical oxidation and electroanalytical determination of xylitol at a boron-doped diamond electrode. Talanta. Feb; 119:509-16. doi: 10.1016/j.talanta.2013.11.030.
Mason, B. (1992). Preparation of soil sampling protocols: Sampling techniques and strategies. U.S. Environmental Protection Agency, Washington, D.C., EPA/600/R-92/128.
https://nepis.epa.gov/Exe/ZyNET.exe/30003W4E.TXT?ZyActionD=ZyDocument&Client=EPA&Index=1991+Thru+1994&Docs=&Query=&Time=&EndTime=&SearchMethod=1&TocRestrict=n&Toc=&TocEntry=&QField=&QFieldYear=&QFieldMonth=&QFieldDay=&IntQFieldOp=0&ExtQFieldOp=0&XmlQuery=&File=D%3A%5Czyfiles%5CIndex%20Data%5C91thru94%5CTxt%5C00000005%5C30003W4E.txt&User=ANONYMOUS&Password=anonymous&SortMethod=h%7C-&MaximumDocuments=1&FuzzyDegree=0& ImageQuality=r75g8/r75g8/x150y150g16/i425&Display=hpfr&DefSeekPage=x&SearchBack=ZyActionL&Back=ZyActionS&BackDesc=Results%20page&MaximumPages=1&ZyEntry=1&SeekPage=x&ZyPURL

Matsumura, F. (1985). Effects of Pesticides on Wildlife. Toxicology of Insecticides, 437–487. https://doi.org/10.1007/978-1-4613-2491-1_10

Mercado, L. A., Freille, S. M., Vaca-Pereira, J. S., Cuellar, M., Flores, L., Mutch, E., Olea, N., y Arrebola, J. P. (2013). Serum concentrations of p,p?-dichlorodiphenyltrichloroethane (p,p?-DDE) in a sample of agricultural workers from Bolivia. Chemosphere, 91(10), 1381–1385. https://doi.org/10.1016/j.chemosphere.2012.12.023

Miller, I., y Werber, M. (1979). Cyclic voltammetry of two Fe-ferredoxins from Halobacterium of the Dead Sea. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 100(1–2), 103–110. https://doi.org/10.1016/s0022-0728(79)80154-0

Molieri J., (1995). Plaguicidas, Salud y Desarrollo Sostenible en Centroamérica. Los Desafíos de la Salud Ambiental. Cuadernos de la Representación OPS/OMS En Panamá (3, 1-76) Panamá: OPS/OMS.

Moreno Fr??As, M., Garrido Frenich, A., Mart??Nez Vidal, J., Mateu Sánchez, M., Olea, F., y Olea, N. (2001). Analyses of lindane, vinclozolin, aldrin, p,p?-DDE, o,p?-DDT and p,p?-DDT

in human serum using gas chromatography with electron capture detection and tandem mass spectrometry. Journal of Chromatography B: Biomedical Sciences and Applications, 760(1), 1–15. https://doi.org/10.1016/s0378-4347(01)00212-2

Narenderan, S., Meyyanathan, S., y Karri, V. V. S. R. (2019). Experimental design in pesticide extraction methods: A review. Food Chemistry, 289, 384–395. https://doi.org/10.1016/j.foodchem.2019.03.045

Pravda, M. (2011). Analytical Methods | Electrochemical Analysis. Encyclopedia of Dairy Sciences, 193–197. https://doi.org/10.1016/b978-0-12-374407-4.00018-2

Ragas, A. M., Oldenkamp, R., Preeker, N., Wernicke, J., y Schlink, U. (2011). Cumulative risk assessment of chemical exposures in urban environments. Environment International, 37(5), 872–881. https://doi.org/10.1016/j.envint.2011.02.015

R?bi?, T., Sobczak, A., Wierzchowski, M., Frankiewicz, A., Te?yk, A., y Milczarek, G. (2018). An approach for electrochemical functionalization of carbon nanotubes/1-amino-9,10-anthraquinone electrode with catechol derivatives for the development of NADH sensors. Electrochimica Acta, 260, 703–715. https://doi.org/10.1016/j.electacta.2017.12.022

Rodríguez J., Lamoth L., (1994). Contaminación de Alimentos de Origen Agrícola con Residuos de Plaguicidas en Panamá. Congreso Latinoamericano de Química (XXI, 1-10) Panamá: Panamá.

Sánchez, J. D. (2015, November). Educación en inocuidad de alimentos: Glosario de términos. Pan American Health Organization / World Health Organization.

https://www3.paho.org/hq/index.php?option=com_content&view=article&id=10433:educacion-inocuidad-alimentos-glosario-terminos-inocuidad-de-alimentos&Itemid=41278&lang=es

Sánchez-Brunete, C., Pérez, R., Miguel, E., y Tadeo, J. (1998). Multiresidue herbicide analysis in soil samples by means of extraction in small columns and gas chromatography with nitrogen–phosphorus and mass spectrometric detection. Journal of Chromatography A, 823(1–2), 17–24. https://doi.org/10.1016/s0021-9673(98)00293-3

Sánchez-Brunete, C., Rodriguez, A., y Tadeo, J. (2003). Multiresidue analysis of carbamate pesticides in soil by sonication-assisted extraction in small columns and liquid chromatography. Journal of Chromatography A, 1007(1–2), 85–91. https://doi.org/10.1016/s0021-9673(03)00953-1

Singh Rathore, H. (2009). Methods of and Problems in Analyzing Pesticide Residues in the Environment. Handbook of Pesticides, 7–46. https://doi.org/10.1201/9781420082470.ch2

Smith, J., Chapman, R., y Frampton, C. (1998). Soil degradation of diazinon and its effect on the emergence of apple leafcurling midge. Proceedings of the New Zealand Plant Protection Conference, 51, 148–151. https://doi.org/10.30843/nzpp.1998.51.11677

Smyth, W. F., y Smyth, M. R. (1987). Electrochemical analysis of organic pollutants. Pure and Applied Chemistry, 59(2), 245–256. https://doi.org/10.1351/pac198759020245

Songa, E. A., y Okonkwo, J. O. (2016). Recent approaches to improving selectivity and sensitivity of enzyme-based biosensors for organophosphorus pesticides: A review. Talanta, 155, 289–304. https://doi.org/10.1016/j.talanta.2016.04.046

Strekopytov, S., Brownscombe, W., Lapinee, C., Sykes, D., Spratt, J., Jeffries, T. E., y Jones, C. G. (2017). Arsenic and mercury in bird feathers: Identification and quantification of inorganic pesticide residues in natural history collections using multiple analytical and imaging techniques. Microchemical Journal, 130, 301–309. https://doi.org/10.1016/j.microc.2016.10.009
Turiel, E., Martín-Esteban, A., y Tadeo, J. L. (2006). Multiresidue analysis of quinolones and fluoroquinolones in soil by ultrasonic-assisted extraction in small columns and HPLC-UV. Analytica Chimica Acta, 562(1), 30–35. https://doi.org/10.1016/j.aca.2006.01.054

Tuzimski, T., yRejczak, T. (2016). Application of HPLC–DAD after SPE/QuEChERS with ZrO 2 -based sorbent in d-SPE clean-up step for
pesticide analysis in edible oils. Food Chemistry, 190, 71–79. https://doi.org/10.1016/j.foodchem.2015.05.072

Uhrov?ík, J. (2014). Strategy for determination of LOD and LOQ values – Some basic aspects. Talanta, 119, 178–180. https://doi.org/10.1016/j.talanta.2013.10.061

Volke T., Velasco J., y De la Rosa D., (2005). Suelos contaminados por metales y metaloides. Instituto Nacional de Ecología. Secretaria de Medio Ambiente y Recursos Naturales. México. 1, 144. Volume 37, Issue 5, 2011, Pages 872-881, ISSN 0160-4120.

Welsch, J., Songling, C., Buckley, H. L., Lehto, N. J., Jones, E. E., y Case, B. S. (2019). How many samples? Soil variability affects confidence in the use of common agroecosystem soil indicators. Ecological Indicators, 102, 401–409. https://doi.org/10.1016/j.ecolind.2019.02.065

Wexler, P. (2014). Encyclopedia of Toxicology (3rd ed.). Academic Press.

Workman, Jerome y Mark, H., (2006). Limitations in analytical accuracy, part I: Horwitz's trumpet. Spectroscopy -Springfield then Eugene then Duluth-. 21. 18-24.

Wu, M., Zhang, L., Wang, D., Xiao, C., y Zhang, S. (2008). Cathodic deposition and characterization of tin oxide coatings on graphite for electrochemical supercapacitors. Journal of Power Sources, 175(1), 669–674. https://doi.org/10.1016/j.jpowsour.2007.09.062